80-A66 - Spray Adhesive

MATERIAL SAFETY DATA SHEET

.

1. Product and Company Identification

space

066-003

Product number Product name space Effective date space

066 Multi Purpose Adhesive Spray 6 Spray Adhesive

11-Feb-2011

space

Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States General Assistance 1-630-628-3000 pray ay, Inc. 484 Vista Ave. ddison, IL 60101 United States

Company information

space

Company phone

space

800-424-9300 703-527-3887

Emergency telephone US

space

Emergency telephone outside US

space

07

Version #

space

28-Jul-2010

Supersedes date

.

2. Hazards Identification

space

Aerosol. EXTREMELY FLAMMABLE CONTENTS UNDER PRESSURE. Will be easily ignited by heat, spark or flames. Irritating to eyes. Prolonged exposure may cause chronic effects.

Emergency overview

Potential health effects space

Skin contact. Ingestion.

Routes of exposure

space

Contact with eyes may cause irritation.

Eyes Skin

space

Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Intentional misuse by concentrating and inhaling the product can be harmful or fatal. Prolonged inhalation may be harmful. Exposure by ingestion of an aerosol is unlikely. May cause delayed lung damage. Components of the product may be absorbed into the body by ingestion. May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. May cause delayed lung damage. Prolonged skin contact may defat the skin and produce dermatitis. Central nervous system. Lungs.

space

Inhalation

space

Ingestion

space

Target organs Chronic effects space

space

Discomfort in the chest. Narcosis. Defatting of the skin. Irritation.

Signs and symptoms

.

3. Composition / Information on Ingredients

space

Components Cyclohexane

CAS #

Percent 30 - 40 15 - 20 10 - 15 10 - 15

110-82-7 106-97-8 115-10-6 74-98-6 75-28-5

n-Butane

Dimethyl Ether

Propane Isobutane

8 - 10

Non-hazardous and other components below reportable levels

10 - 20

. From the library of: Superior Sewing Machine & Supply LLC 4. First Aid Measures

space

First aid procedures

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops or persists. Immediately take off all contaminated clothing. Wash off with warm water and soap. Get medical attention if irritation develops or persists.

Eye contact

space

Skin contact

space

Move to fresh air. If symptoms persist, get medical attention.

Inhalation

Product name: 066 Multi Purpose Adhesive Spray Product #: 066-003 Revision date: 11-FEB-2011 Print date: 11-FEB-2011 66 Spray Adhesive

MSDS US 1 / 5

space

If material is ingested, immediately contact a poison control center. Have victim rinse mouth thoroughly with water. Do not induce vomiting without advice from poison control center. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.

Ingestion

space

Symptoms may be delayed.

Notes to physician

.

5. Fire Fighting Measures

space

Vapor or gas may spread to distant ignition sources and flash back. Runoff to sewer may cause fire or explosion hazard.

Flammable properties

Extinguishing media space

Foam. Dry chemical. Carbon dioxide (CO2). Do not use water jet. Water may be ineffective.

Suitable extinguishing media

Protection of firefighters space

Fire may produce irritating, corrosive and/or toxic gases.

Specific hazards arising from the chemical Protective equipment and precautions for firefighters

space

In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Containers should be cooled with water to prevent vapor pressure build up. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

.

6. Accidental Release Measures

space

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into waterways, sewers, basements or confined areas. Should not be released into the environment. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. Pressurized container: Do not pierce or burn, even after use. Do not handle or store near an open flame, heat or other sources of ignition. Do not smoke while using or until sprayed surface is thoroughly dry. Do not use if spray button is missing or defective. Use only with adequate ventilation. Do not get this material in contact with eyes. Do not get this material in contact with skin. Wear personal protective equipment. Avoid prolonged exposure. 7. Handling and Storage Level 3 Aerosol. Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed containers can increase under the influence of heat. Do not handle or store near an open flame, heat or other sources of ignition. Avoid exposure to long periods of sunlight. Store in cool place. Keep in an area equipped with sprinklers. Keep out of the reach of children. Level 3 Aerosol. Do not store, incinerate, or heat this material above 120 degrees Fahrenheit.

Methods for containment

space

Methods for cleaning up

.

space

Handling

space

Storage

.

8. Exposure Controls / Personal Protection

space

Exposure limits ACGIH Components

CAS # From the library of: Superior Sewing Machine & Supply LLC

TWA 100 ppm 1000 ppm 1000 ppm 1000 ppm

STEL Not established Not established Not established Not established

Ceiling Not established Not established Not established Not established

Cyclohexane

110-82-7 106-97-8 74-98-6 75-28-5

n-Butane Propane space Isobutane

Product name: 066 Multi Purpose Adhesive Spray Product #: 066-003 Revision date: 11-FEB-2011 Print date: 11-FEB-2011 66 Spray Adhesive

MSDS US 2 / 5

space

OSHA Components Cyclohexane

CAS #

TWA 300 ppm 1000 ppm

STEL Not established Not established

Ceiling Not established Not established

110-82-7 74-98-6

space Propane

Personal protective equipment space

Wear chemical goggles.

Eye / face protection

space

Wear appropriate chemical resistant clothing. Protective gloves.

Skin protection

space

When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

Respiratory protection

.

9. Physical & Chemical Properties

space

Compressed liquefied gas. 64.4 °F (17.8 °C) estimated

Appearance Boiling point space

space

Tan.

Color

space

0.6689 g/cm3 estimated 42.4775 kJ/g estimated

Density

space

Flammability (HOC)

space

Yes

Flash back Flash point space

-156 °F (-104.4 °C) Propellant

space

Liquid. Aerosol. Not available

Form

space

Freezing point

space

Solvent.

Odor

space

Not applicable

pH space

Liquid.

Physical state

space

55 - 75 psig @ 70F

Pressure Solubility space

None 0.669

space

Specific gravity

.

10. Chemical Stability & Reactivity Information

space

Risk of ignition.

Chemical stability Conditions to avoid space

Heat, flames and sparks.

Hazardous decomposition products No hazardous decomposition products are known. space

.

11. Toxicological Information

space

Acute LD50: 5244 mg/kg estimated, Rat, Dermal

Acute effects

space

Component analysis - LD50

Toxicology Data - Selected LD50s and LC50s 110-82-7 Cyclohexane

Inhalation LC50 Rat 13.9 mg/L 4 h; Oral LD50 Rat >5000 mg/kg; Dermal LD50 Rabbit >2000 mg/kg

Dimethyl Ether

115-10-6 75-28-5 106-97-8 74-98-6

Inhalation LC50 Rat 308.5 mg/L 4 h Inhalation LC50 Rat 658 mg/L 4 h Inhalation LC50 Rat 658 mg/L 4 h Inhalation LC50 Rat 658 mg/L 4 h

Isobutane n-Butane Propane

space

Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by OSHA criteria.

Sensitization Teratogenicity space

.

12. Ecological Information From the library of: Superior Sewing Machine & Supply LLC

space

Components of this product are hazardous to aquatic life. LC50 11.98 mg/L, Fish, 96.00 Hours, IC50 1322 mg/L, Algae, 72.00 Hours,

Ecotoxicity

.

13. Disposal Considerations

space

D001: Waste Flammable material with a flash point <140 F

Waste codes

Product name: 066 Multi Purpose Adhesive Spray Product #: 066-003 Revision date: 11-FEB-2011 Print date: 11-FEB-2011 66 Spray Adhesive

MSDS US 3 / 5

space

Contents under pressure. Do not puncture, incinerate or crush. Dispose of this material and its container at hazardous or special waste collection point. Do not allow this material to drain into sewers/water supplies. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose in accordance with all applicable regulations.

Disposal instructions

.

14. Transport Information

space

Department of Transportation (DOT) Requirements

Hazard class Subsidiary hazard class Proper shipping name Basic shipping requirements:

Consumer commodity ORM-D None

Packaging exceptions Packaging non bulk Packaging bulk Additional information:

156, 306 156, 306 None

space

IMDG

Hazard class UN number Proper shipping name Basic shipping requirements:

AEROSOLS 2.1 1950

Packaging exceptions Item Labels required Transport Category Additional information:

LTD QTY 5F None 2

space

IATA

Hazard class UN number Proper shipping name Basic shipping requirements:

Aerosols, flammable 2.1 1950

Packaging exceptions Labels required Additional information:

LTD QTY 2.1

.

15. Regulatory Information

space

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

US federal regulations

U.S. - CERCLA/SARA - Section 313 - Emission Reporting 110-82-7 Cyclohexane Yes Occupational Safety and Health Administration (OSHA) space 29 CFR 1910.1200 hazardous chemical

1.0 % de minimis concentration

Cyclohexane: 1000.0000 CERCLA (Superfund) reportable quantity space

No Superfund Amendments and Reauthorization Act of 1986 (SARA) space From the library of: Superior Sewing Machine & Supply LLC

Section 302 extremely hazardous substance

Section 311 hazardous chemical Yes space Hazard categories (311/312) space

Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No

Product name: 066 Multi Purpose Adhesive Spray Product #: 066-003 Revision date: 11-FEB-2011 Print date: 11-FEB-2011 66 Spray Adhesive

MSDS US 4 / 5

space

Inventory status

Country(s) or region

Inventory name

On inventory (yes/no)* No No No No No

China Europe Europe Japan Korea

Inventory of Existing Chemical Substances in China (IECSC) European Inventory of New and Existing Chemicals (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL)

Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

space

State regulations

U.S. - Pennsylvania - RTK (Right to Know) List 110-82-7 Cyclohexane

Environmental hazard

Dimethyl Ether

115-10-6 75-28-5 106-97-8 74-98-6

Present Present Present Present

Isobutane n-Butane Propane

.

16. Other Information

space

HMIS® is a registered trade and service mark of the NPCA.

Further information

space

Health: 1* Flammability: 4 Physical hazard: 0

HMIS® ratings

space

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Disclaimer

space

Product and Company Identification: Product and Company Identification

MSDS sections updated

space

Regulatory Compliance

Prepared by

From the library of: Superior Sewing Machine & Supply LLC

Product name: 066 Multi Purpose Adhesive Spray Product #: 066-003 Revision date: 11-FEB-2011 Print date: 11-FEB-2011 66 Spray Adhesive

MSDS US 5 / 5