CHLORINE DIOXIDE (ClO
2
)
Though it has Chlorine in its name, the chemistry of ClO
2
is radically different from that
of Chlorine.
ClO
2
is generally accepted to be more powerful, easier to use, and more environmentally
friendly than equivalent Chlorine treatments.
ClO
2
is less corrosive than Chlorine and almost negligible at use concentrations.
As an electron receiver, ClO
2
is an oxidizer. However ClO
2
has the ability to absorb 5
electrons whereas Chlorine can only absorb 2 electrons. This makes Chlorine Dioxide
chemically 2.5 times more active than Chlorine.
Unlike other disinfectants acting
dominantly on cell walls, ClO
2
penetrates into cells, displaying a high affinity for sulfur
and hydrogen bonds of proteins destroying the organisms.
In addition ClO
2
reacts
directly with the amino acids and RNA of a cell, killing microorganisms even when they
are inactive.
ClO
2
is effective against Giardia and Cryptosporidium oocysts, and all bacteria, viruses
and spore formers at 0.1 ppm to 100 ppm. It is effective against anthrax at 20 ppm.
ClO
2
has a neutral pH.
Biocidal properties are not influenced by pH. As a result ClO
2
rapidly inactivates most
microorganisms over a wide pH range.
Many researchers have cited the excellent biofilm removing properties of ClO
2
. Chlorine
Dioxide effectively penetrates and disperses the “polysaccharide glue” of biofilm. By
effectively killing and stripping off biofilm, bacteria are much slower to reestablish than
when biofilm is left intact. This is something most other disinfectants have particular
problems doing!
Unlike Chlorine, ClO
2
will not adversely react with organic compounds and as a result
ClO
2
does not produce unwanted carcinogenic chlorinated volatile organic compounds
(VOC) and trihalomines. In fact, instead of combining with the aromatic rings of organic
compounds, ClO
2
actually breaks these rings apart reducing levels of chlorinated
organics. This makes ClO
2
use environmentally sparing! Also, because ClO
2
does not
react or combine with organic compounds, much more of it remains available as a
biocidal agent.
ClO
2
can be used for odor control and air disinfection, and was the principal agent used
in the decontamination of buildings in the United States after the 2001 anthrax attacks.
ClO
2
is highly soluble in H
2
O, in fact it is 10 times more soluble than Chlorine, i.e., ClO
2
loves and looks for water/moisture.
In neutral or near neutral solutions (4< pH <10)
chlorine dioxide is relatively stable and exists as a free radical in water.
ClO
2
generation forms byproducts of chlorite and chlorate, decomposes in sunlight and is
highly biodegrabable.