SDS - Online Packet 10-5-2018

December 21, 2023

ATTENTION CONTRACTORS:

The Safety Data Sheets (SDS) for the Building Division Products you are using, or may be using, are enclosed in this packet. You should be aware of the potential hazards, proper handling techniques, and use of any products that you are using. This packet contains updated SDS information for most of the products you could receive. You may or may not be using all of these products for your projects. Chief Industries, Inc. urges you, and it is your duty, under the Federal Hazard Communication Standard (29CFR 1910, 1200) and any applicable state and/or local right-to-know regulations, to pass the warnings and information on the enclosed SDS(s) along to your employees, customers, handlers, and/or users of these products. Even though Chief Industries, Inc. is forwarding this information to you, it is not necessarily all encompassing; therefore, it is recommended that you consult with knowledgeable people of your choice in order to determine whether your safety programs and warnings are adequate and/or in compliance with any applicable laws and regulations.

Below is a list of SDS(s) contained in this packet. Refer to your shipping papers for the products that you are using and reference the appropriate SDS(s).

I. Gray Primer. II. Sika Mastic (201) and (511) sealants. III. Touch-up paints (All standard colors). IV. Zink Coatings

ENCLOSURES

Last Revision: 12/21/2023

Section I

Gray Primer

SAFETY DATA SHEET

Revision date 02-Sep-2022

Version 14

Supersedes Date: 31-Jul-2021

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product identifier Product Code

KMAA148

VECTROCOAT 300 GREY

Product Name

Other means of identification No information available

Recommended use of the chemical and restrictions on use Paint, Coatings

Details of the supplier of the safety data sheet See section 16 for more information

The Sherwin-Williams Company 101 W. Prospect Avenue Cleveland, OH 44115

msds@valspar.com

E-mail address

Emergency telephone number United States of America 1-888-345-5732

Section 2: HAZARDS IDENTIFICATION

Classification

Skin corrosion/irritation

Category 2 Category 2 Category 1 Category 1 Category 3

Serious eye damage/eye irritation

Skin sensitization

Specific target organ toxicity (repeated exposure)

Flammable liquids

Label elements

Signal word

DANGER

HAZARD STATEMENTS Flammable liquid and vapor

Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction Causes damage to organs through prolonged or repeated exposure

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AGHS - USA OSHA SDS

Product Code KMAA148

PREVENTION Wash face, hands and any exposed skin thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. RESPONSE Get medical advice/attention if you feel unwell. Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin If skin irritation or rash occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse. Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Fire In case of fire: Use CO2, dry chemical, or foam for extinction.

STORAGE Store in a well-ventilated place. Keep cool.

DISPOSAL Dispose of contents/containers in accordance with local regulations.

HAZARDS NOT OTHERWISE CLASSIFIED (HNOC) No information available.

OTHER HAZARDS Not applicable.

0% of the mixture consists of ingredient(s) of unknown toxicity.

UNKNOWN ACUTE TOXICITY

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Titanium dioxide 2-Butoxyethanol Proprietary Inert

CAS No

weight-%

13463-67-7

10 - 25 10 - 25

111-76-2

Proprietary 107-98-2 110-97-4 104-76-7 1333-86-4 Proprietary

3 - 5 3 - 5 3 - 5 3 - 5

Propylene glycol monomethyl ether

Diisopropanolamine

2-Ethylhexanol Carbon black Epoxy Resin Formaldehyde

0.3 - 1 0.3 - 1

50-00-0

10 - 100 ppm

*The exact percentage (concentration) of composition has been withheld as a trade secret.

Section 4: FIRST AID MEASURES

First Aid Measures

General advice Get medical advice/attention if you feel unwell.

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AGHS - USA OSHA SDS

Product Code KMAA148

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact If skin irritation or rash occurs: Get medical advice/attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. Wash contaminated clothing before reuse.

Inhalation IF INHALED: Call a POISON CENTER or doctor if you feel unwell.

Ingestion Do NOT induce vomiting. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Most important symptoms and effects, both acute and delayed

No information available.

Symptoms

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Note to physicians

Section 5: FIRE FIGHTING MEASURES

Suitable extinguishing media Dry chemical, CO2, water spray or alcohol-resistant foam.

Not to be used for safety reasons: Strong water jet

Specific hazards arising from the chemical Burning produces heavy smoke. Fire may produce irritating and/or toxic gases. In the event of fire and/or explosion do not breathe fumes. May cause sensitization by skin contact. Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit. Cool containers with flooding quantities of water until well after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid breathing vapors or mists. Remove all sources of ignition. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak. Evacuate personnel to safe areas. Take precautionary measures against static discharges.

For emergency responders Use personal protection recommended in Section 8.

Environmental precautions

Do not allow into any sewer, on the ground or into any body of water. If the product contaminates lakes, rivers or sewage, inform appropriate authorities in accordance with local regulations. Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Dispose of waste product or used containers according to local regulations. Clean with detergents. Avoid solvent cleaners. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Take up mechanically, placing in

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AGHS - USA OSHA SDS

Product Code KMAA148

appropriate containers for disposal. Pick up and transfer to properly labeled containers.

Section 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Prevent the creation of flammable or explosive concentrations of vapor in air and avoid vapor concentration higher than the occupational exposure limits. Operators should wear anti-static footwear and clothing and floors should be of the conducting type. Use personal protection recommended in Section 8. Never use pressure to empty container. Comply with the health and safety at work laws. Prevent product from entering drains. Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. All equipment used when handling the product must be grounded.

General Hygiene Considerations Avoid contact with skin, eyes or clothing. When using do not eat, drink or smoke. Wash contaminated clothing before reuse.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep/store only in original container. Store in accordance with local regulations. Keep unauthorized personnel away. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Keep tightly closed in a dry and cool place.

Incompatible materials Strong oxidizing agents. Acids.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Limits If S* appears in the OEL table, it indicates this chemical contains a skin notation.

Chemical Name Titanium dioxide 13463-67-7 2-Butoxyethanol 111-76-2

ACGIH TLV

OSHA PEL

NIOSH IDLH

TWA: 10 mg/m 3

TWA: 15 mg/m 3 total dust

IDLH: 5000 mg/m 3

TWA: 20 ppm

TWA: 50 ppm TWA: 240 mg/m 3 S*

IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m 3

Proprietary Inert

TWA: 2 mg/m 3 particulate matter containing no asbestos and <1% crystalline silica, respirable particulate matter

TWA: 20 mppcf if 1% Quartz or more;use Quartz limit

IDLH: 1000 mg/m 3 TWA: 2 mg/m 3 containing no Asbestos and <1% Quartz respirable dust

Propylene glycol monomethyl ether 107-98-2

STEL: 100 ppm TWA: 50 ppm

TWA: 100 ppm TWA: 360 mg/m 3 STEL: 150 ppm STEL: 540 mg/m 3 IDLH: 1750 mg/m 3 TWA: 3.5 mg/m 3

Carbon black 1333-86-4

TWA: 3 mg/m 3 inhalable particulate matter

TWA: 3.5 mg/m 3

TWA: 0.1 mg/m 3 Carbon black in presence of Polycyclic aromatic hydrocarbons PAH

Formaldehyde 50-00-0

Ceiling: 0.3 ppm

TWA: 0.75 ppm STEL: 2 ppm see 29 CFR 1910.1048

IDLH: 20 ppm Ceiling: 0.1 ppm 15 min TWA: 0.016 ppm

Appropriate engineering controls

Engineering Controls Ensure adequate ventilation, especially in confined areas. Provide local exhaust ventilation. In case of insufficient ventilation, wear suitable respiratory equipment.

Individual protection measures, such as personal protective equipment

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AGHS - USA OSHA SDS

Product Code KMAA148

Eye/face protection Tight sealing safety goggles.

Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Wear suitable protective clothing. Personnel should wear anti-static clothing made of natural fiber or of high temperature resistant synthetic fiber. Hand Protection There is no one glove material or combination of materials that will give unlimited resistance to any individual or combination of chemicals. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. The instructions and information provided by the glove manufacturer on use, storage, maintenance and replacement must be followed. Gloves should be replaced regularly and if there is any sign of damage to the glove material. Always ensure that gloves are free from defects and that they are stored and used correctly. The performance or effectiveness of the glove may be reduced by physical / chemical damage and poor maintenance. Wear protective gloves.

Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Thermal Protection No information available

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

liquid

Physical state Appearance

No information available

Solvent

Odor Color

grey

No information available No information available No information available

Odor Threshold

pH value

Melting point/freezing point Boiling point / boiling range

No information available °C / °F

48 °C / 118 °F

flash point

No information available No information available

evaporation rate

Flammability (solid, gas) Flammability Limit in Air

No information available No information available No information available No information available

Upper flammability limit: Lower flammability limit:

Vapor Pressure vapor density

10.74

Density (lbs per US gallon)

1.29

specific gravity Solubility(ies)

No information available No information available No information available No information available No information available No information available

Partition coefficient

Autoignition temperature Decomposition temperature

Kinematic viscosity Dynamic viscosity

Other information

Section 10: STABILITY AND REACTIVITY

No information available.

Reactivity

Stable under normal conditions.

Chemical stability

Possibility of Hazardous Reactions None under normal processing.

None under normal processing.

Hazardous polymerization

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AGHS - USA OSHA SDS

Product Code KMAA148

Heat, flames and sparks.

Conditions to avoid

Strong oxidizing agents. Acids.

Incompatible materials

Hazardous Decomposition Products Carbon monoxide. Carbon dioxide (CO2). Nitrogen oxides (NOx).

Section 11: TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Eye contact Causes serious eye irritation Skin Contact May cause an allergic skin reaction Causes skin irritation Ingestion Not applicable Inhalation Not applicable

Numerical measures of toxicity - Component Information

Chemical Name Titanium dioxide 13463-67-7 2-Butoxyethanol 111-76-2 Proprietary Inert

Oral LD50

Dermal LD50

Inhalation LC50

> 10000 mg/kg ( Rat )

-

-

= 470 mg/kg ( Rat )

= 99 mg/kg ( Rabbit )

= 450 ppm ( Rat ) 4 h

-

-

-

Propylene glycol monomethyl ether 107-98-2

= 5000 mg/kg ( Rat )

= 13 g/kg ( Rabbit )

> 7559 ppm ( Rat ) 6 h

Diisopropanolamine 110-97-4

= 4765 mg/kg ( Rat )

= 8000 mg/kg ( Rabbit )

-

2-Ethylhexanol 104-76-7 Carbon black 1333-86-4 Epoxy Resin

= 3730 mg/kg ( Rat )

= 1980 mg/kg ( Rabbit )

> 227 ppm ( Rat ) 6 h

> 15400 mg/kg ( Rat )

> 3 g/kg ( Rabbit )

-

-

-

-

Formaldehyde 50-00-0

= 100 mg/kg ( Rat )

= 270 mg/kg ( Rabbit )

= 0.578 mg/L ( Rat ) 4 h

Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 7610 Mg/kg ATEmix (dermal) 7691 Mg/kg ATEmix (inhalation-dust/mist) 8.6 mg/l ATEmix (inhalation-vapor) 63 mg/l

0% of the mixture consists of ingredient(s) of unknown toxicity.

UNKNOWN ACUTE TOXICITY

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Carcinogenicity According to IARC, Volume 93, no significant exposure to primary particles of titanium dioxide is thought to occur from use in paints since the pigment is bound to other materials. According to IARC, Volume 93, no significant exposure to primary particles of carbon black is thought to occur from use in paints since the pigment is bound to other materials. Chemical Name ACGIH IARC NTP OSHA Titanium dioxide 13463-67-7 Group 2B X 2-Butoxyethanol 111-76-2 A3 Carbon black 1333-86-4 A3 Group 2B X

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AGHS - USA OSHA SDS

Product Code KMAA148

A2

Known

X

Formaldehyde 50-00-0

Group 1

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen. A2 - Suspected Human Carcinogen. IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans. Group 1 - Carcinogenic to Humans. NTP (National Toxicology Program) Known - Known Carcinogen. OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present.

Skin corrosion/irritation Causes skin irritation Serious eye damage/eye irritation Causes serious eye irritation Skin sensitization May cause an allergic skin reaction

Respiratory sensitization Not applicable Germ cell mutagenicity Not applicable Carcinogenicity Not applicable Reproductive Toxicity Not applicable Specific target organ toxicity (single exposure) Not applicable Specific target organ toxicity (repeated exposure) Causes damage to organs through prolonged or repeated exposure Aspiration hazard Not applicable

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity Environmental precautions

Prevent product from entering drains.

Persistence and degradability No information available

Bioaccumulation No information available

Mobility No information available

No information available

Other adverse effects

Section 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Disposal of wastes

Improper disposal or reuse of this container may be dangerous and illegal. Empty containers must be scrapped or reconditioned.

Contaminated packaging

Section 14: TRANSPORT INFORMATION

DOT

IMDG

IATA

UN1263

UN1263

UN1263

14.1 UN/ID no

Paint

Paint

Paint

14.2 Proper shipping name

COMBUSTIBLE LIQUID

3

3

14.3 Hazard Class 14.4 Packing Group

III

III

III

14.5 Environmental hazard 14.6 Special Provisions

367, B1, B52, B131, IB3, T2, TP1, TP29 Emergency Response Guide Number 128

163, 223, 367, 955 EmS-No F-E, S-E

A3, A72, A192

No information available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

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AGHS - USA OSHA SDS

Product Code KMAA148

The supplier may apply one of the following exceptions: Combustible Liquid (49 CFR 173.150(f)); Consumer Commodity (49 CFR 173.150(c), ICAO/IATA SP A112); Limited Quantity (49 CFR 173.150(b), ICAO Part 3 Chapter 4, IATA 2.7, IMDG Chapter 3.4); Viscous Liquid (49 CFR 173.121(b), IMDG 2.3.2.2, IATA 3.3.3.1.1, ICAO 3.2.2, ADR 2.2.3.1.5); Does Not Sustain Combustion (49 CFR 173.120(a), IATA 3.3.1.3, ICAO 3.1.3, IMDG 2.3.1.3, ADR 2.2.3.1.1 Note 1); or others as allowed under hazardous materials/dangerous goods regulations.

Section 15: REGULATORY INFORMATION

International Inventories TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

All components are listed or exempt from listing. (Active List). All components are listed or exempt from listing

DSL - Canadian Domestic Substances List

US Federal Regulations

Chemical Name

SARA 313 - Threshold Values %

Metals

Hazardous air pollutants (HAPs) content

2-Butoxyethanol 111-76-2 10 - 25

1

Chemical Name

CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants

CWA - Hazardous Substances

Formaldehyde 50-00-0

100 lb

X

Chemical Name Formaldehyde 50-00-0

Hazardous Substances RQs

CERCLA/SARA RQ

Reportable Quantity (RQ)

100 lb

100 lb

RQ 100 lb final RQ RQ 45.4 kg final RQ

US State Regulations

Rule 66 status of product Not photochemically reactive.

California Proposition 65 WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

U.S. EPA Label information

EPA Pesticide registration number Not applicable

U.S. State Right-to-Know Regulations

Chemical Name Proprietary Non-Hazardous Ingredient - Proprietary CAS

.

.

Titanium dioxide 13463-67-7 2-Butoxyethanol 111-76-2

.

.

Proprietary Non-Hazardous Ingredient - Proprietary CAS

.

Proprietary Inert

.

Propylene glycol monomethyl ether 107-98-2

.

Diisopropanolamine 110-97-4

.

Proprietary Non-Hazardous Ingredient - Proprietary CAS

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AGHS - USA OSHA SDS

Product Code KMAA148

.

2-Ethylhexanol 104-76-7

.

Strontium chromate 7789-06-2

Section 16: OTHER INFORMATION

HMIS Health hazards

3*

* = Chronic Health Hazard

2 0 X

Flammability

Physical hazards Personal Protection

Supplier Address

Valspar Coatings 5400 Avenue Of The Cities Moline, IL 61265 309-762-7546

Product Stewardship

Prepared By

02-Sep-2022

Revision date Revision Note

No information available

Disclaimer The information on this Safety Data Sheet (SDS) is based on the present state of our knowledge, current national legislation and guidelines. As the specific conditions of use of the product are outside the supplier's knowledge and control the user is responsible for ensuring that the requirements of relevant legislation are complied with. This SDS should not be construed as any guarantee of the technical performance or suitability for particular applications. UNLESS SUPPLIER AGREES OTHERWISE IN WRITING, SUPPLIER MAKES NO WARRANTIES, EXPRESS OR IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. SUPPLIER WILL NOT BE LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES.

End of Safety Data Sheet

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Product Code KMAA148

Section II

Mastics

Safety Data Sheet SikaLastomer®‐95 

Revision Date 08/28/2014

Print Date 08/28/2014

1. Identification

Product name

: SikaLastomer®‐95

Supplier

: Sika Corporation

Address

: 201 Polito Avenue

Lyndhurst, NJ 07071 USA www.sikausa.com

Telephone

: (201) 933-8800

Telefax

: (201) 804-1076

Emergency telephone

: CHEMTREC: 800-424-9300 INTERNATIONAL: 703-527-3887 ehs@sika-corp.com

: For further information, refer to the product technical data sheet.

Recommended use of the chemical and restrictions on use

2. Hazards identification

GHS Classification

Not a hazardous substance or mixture.

GHS Label element Not a hazardous substance or mixture. See Section 11 for more detailed information on health effects and symptoms.

3. Composition/information on ingredients

Hazardous ingredients There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

4. First aid measures If inhaled

: Move to fresh air.

In case of skin contact

: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water.

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Safety Data Sheet SikaLastomer®‐95 

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In case of eye contact

: Flush eyes with water as a precaution. Remove contact lenses. Keep eye wide open while rinsing.

If swallowed

: Clean mouth with water and drink afterwards plenty of water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person.

Most important symptoms and effects, both acute and delayed

: No known significant effects or hazards.

See Section 11 for more detailed information on health effects and symptoms.

Protection of first-aiders

: No hazards which require special first aid measures.

Notes to physician

: Treat symptomatically.

5. Fire-fighting measures Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Specific hazards during fire fighting

: none

: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Specific extinguishing methods

Special protective equipment for fire-fighters

: In the event of fire, wear self-contained breathing apparatus.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions

: Refer to protective measures listed in sections 7 and 8.

: Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Keep in suitable, closed containers for disposal.

7. Handling and storage

Advice on safe handling

: For personal protection see section 8. No special handling advice required. Follow standard hygiene measures when handling chemical products.

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Safety Data Sheet SikaLastomer®‐95 

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Conditions for safe storage

: Keep container tightly closed in a dry and well-ventilated place. Store in accordance with local regulations.

Materials to avoid

: no data available

8. Exposure controls/personal protection Contains no substances with occupational exposure limit values. Engineering measures

: Use of adequate ventilation should be sufficient to control worker exposure to airborne contaminants. If the use of this product generates dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. : Use a properly fitted NIOSH approved air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapor/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. : Wash hands before breaks and immediately after handling the product. Remove contaminated clothing and protective equipment before entering eating areas. Avoid breathing dust.

Personal protective equipment Respiratory protection

Hand protection Remarks

Eye protection

Skin and body protection

Hygiene measures

9. Physical and chemical properties Appearance

: solid : gray

Color

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Safety Data Sheet SikaLastomer®‐95 

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Odor

: odorless

Odor Threshold

: no data available

Flash point

: > 399 °F (> 204 °C)

Ignition temperature : no data available Decomposition temperature : no data available Lower explosion limit (Vol%) : no data available Upper explosion limit (Vol%) : no data available Flammability (solid, gas) : no data available Oxidizing properties : no data available Autoignition temperature : no data available pH : Note: not applicable Melting point/range / Freezing point : no data available Boiling point/boiling range : no data available Vapor pressure : no data available Density : ca.1.5 g/cm3 at 73 °F (23 °C) Water solubility : Note: insoluble Partition coefficient: n octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : Note: not applicable Relative vapor density : no data available Evaporation rate : no data available Burning rate : no data available Volatile organic compounds (VOC) content : not applicable

10. Stability and reactivity Reactivity

: No dangerous reaction known under conditions of normal use.

Chemical stability

: The product is chemically stable.

Possibility of hazardous reactions

: Stable under recommended storage conditions.

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Conditions to avoid

: no data available

Incompatible materials

: no data available

Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.

11. Toxicological information

Acute toxicity Product

Acute oral toxicity

: no data available

Acute inhalation toxicity

: no data available

Acute dermal toxicity

: no data available

Skin corrosion/irritation Product no data available

Serious eye damage/eye irritation Product no data available Respiratory or skin sensitization Product no data available

Germ cell mutagenicity Product Mutagenicity

: no data available

Carcinogenicity Product

Carcinogenicity

: no data available

IARC

not applicable not applicable

NTP

Reproductive Toxicity/Fertility Product Reproductive toxicity

: no data available

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Safety Data Sheet SikaLastomer®‐95 

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Reproductive Toxicity/Development/Teratogenicity Product Teratogenicity : no data available

STOT-single exposure Product

Assessment: no data available

STOT-repeated exposure

Product Assessment: no data available

Aspiration toxicity Product

no data available

12. Ecological information Other information

Do not empty into drains; dispose of this material and its container in a safe way.

13. Disposal considerations Disposal methods Waste from residues

: Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. : Empty containers should be taken to an approved waste handling site for recycling or disposal.

Contaminated packaging

14. Transport information

DOT Not dangerous goods IATA Not dangerous goods IMDG

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Safety Data Sheet SikaLastomer®‐95 

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Not dangerous goods Special precautions for user no data available Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable

15. Regulatory information

TSCA list

: All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.

EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA304 Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : No SARA Hazards

SARA 302

: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 313

Clean Air Act

Ozone-Depletion Potential This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

16. Other information

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Safety Data Sheet SikaLastomer®‐95 

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HMIS Classification

Physical Hazard Flammability Personal Protection Health

1

0

0

X

Caution: HMIS® rating is based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® rating is not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® rating is to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). Please note HMIS® attempts to convey full health warning information to all employees. Notes to Reader The information contained in this Safety Data Sheet applies only to the actual Sika Corporation ("Sika") product identified and described herein. This information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material, product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current Product Data Sheet, product label and Safety Data Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this SDS. SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY OTHERS. All sales of Sika products are subject to its current terms and conditions of sale available at www.sikausa.com or 201-933-8800.

Revision Date 08/28/2014 Material number: 132730

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

1. Identification

Product name

: Sikaflex®‐201 US

Supplier

: Sika Corporation

: 201 Polito Avenue

Address

Lyndhurst, NJ 07071 USA www.sikausa.com

: (201) 933-8800

Telephone

: (201) 804-1076

Telefax

Emergency telephone

: CHEMTREC: 800-424-9300 INTERNATIONAL: 703-527-3887 ehs@sika-corp.com

Recommended use of the chemical and restrictions on use

: For further information, refer to the product technical data sheet.

2. Hazards identification

GHS Classification Respiratory sensitization, Category 1

H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317: May cause an allergic skin reaction.

Skin sensitization, Category 1 Carcinogenicity, Category 1A

H350: May cause cancer.

GHS Label element Hazard pictograms

:

: Danger

Signal Word

Hazard Statements

: H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 May cause cancer. : Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. P281 Use personal protective equipment as required.

Precautionary Statements

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

P285 In case of inadequate ventilation wear respiratory protection. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P363 Wash contaminated clothing before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. : Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by deliberate concentration and inhalation of vapors may be harmful or fatal.

Warning

See Section 11 for more detailed information on health effects and symptoms.

3. Composition/information on ingredients

Hazardous ingredients Chemical Name

CAS-No.

Concentration (%)

titanium dioxide

13463-67-7 1330-20-7 100-41-4 14808-60-7 53317-61-6 1333-86-4 101-68-8

>= 2 - < 5 % >= 2 - < 5 % >= 0 - < 1 % >= 0 - < 1 % >= 0 - < 1 % >= 0 - < 1 %

xylene

ethylbenzene Quartz (SiO2)

aromatic polyisocyanate

Carbon black

4,4'-methylenediphenyl diisocyanate >= 0 - < 1 % There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

4. First aid measures If inhaled

: Move to fresh air. Consult a physician after significant exposure. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician.

In case of skin contact

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

: Remove contact lenses. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

In case of eye contact

If swallowed

: Clean mouth with water and drink afterwards plenty of water. Induce vomiting immediately and call a physician. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. : Asthmatic appearance Allergic reactions See Section 11 for more detailed information on health effects and symptoms. sensitizing effects carcinogenic effects : Move out of dangerous area. Consult a physician. Show this material safety data sheet to the doctor in attendance.

Most important symptoms and effects, both acute and delayed

Protection of first-aiders

Notes to physician

: Treat symptomatically.

5. Fire-fighting measures Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Specific extinguishing methods

: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for fire-fighters

: In the event of fire, wear self-contained breathing apparatus.

6. Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions

: Use personal protective equipment. Deny access to unprotected persons.

: Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Local authorities should be advised if significant spillages cannot be contained. : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

Methods and materials for containment and cleaning up

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

7. Handling and storage

Advice on safe handling

: Do not breathe vapors or spray mist. Avoid exceeding the given occupational exposure limits (see section 8). Do not get in eyes, on skin, or on clothing. For personal protection see section 8. Persons with a history of skin sensitization problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. Smoking, eating and drinking should be prohibited in the application area. Follow standard hygiene measures when handling chemical products. : Prevent unauthorized access. Store in original container. Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Store in accordance with local regulations.

Conditions for safe storage

Materials to avoid

: no data available

8. Exposure controls/personal protection Component CAS-No.

Basis **

Value Exposure limit(s)* / Form of exposure

xylene

1330-20-7

OSHA Z-1

TWA

100 ppm 435 mg/m3

ACGIH

TWA

100 ppm

ACGIH

STEL

150 ppm

OSHA P0

STEL

150 ppm 655 mg/m3 100 ppm 435 mg/m3

OSHA P0

TWA

ethylbenzene

100-41-4

ACGIH

TWA

100 ppm

ACGIH

STEL

125 ppm

OSHA Z-1

TWA

100 ppm 435 mg/m3 100 ppm 435 mg/m3

OSHA P0

TWA

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

OSHA P0

STEL

125 ppm 545 mg/m3

*The above mentioned values are in accordance with the legislation in effect at the date of the release of this safety data sheet. ** Basis ACGIH. Threshold Limit Values (TLV) OSHA P0. Table Z-1, Limit for Air Contaminat (1989 Vacated Values) OSHA P1. Permissible Exposure Limits (PEL), Table Z-1, Limit for Air Contaminant OSHA P2. Permissible Exposure Limits (PEL), Table Z-2 OSHA Z3. Table Z-3, Mineral Dust

Engineering measures

: Use of adequate ventilation should be sufficient to control worker exposure to airborne contaminants. If the use of this product generates dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. : Use a properly fitted NIOSH approved air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapor/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary. : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Remove contaminated clothing and protective equipment before entering eating areas. Wash thoroughly after handling.

Personal protective equipment Respiratory protection

Hand protection Remarks

Eye protection

Skin and body protection

Hygiene measures

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

9. Physical and chemical properties Appearance

: paste : various

Color

Odor

: aromatic

Odor Threshold

: no data available

Flash point

: Note: not applicable

Ignition temperature : not applicable Decomposition temperature : no data available Lower explosion limit (Vol%) : no data available Upper explosion limit (Vol%) : no data available Flammability (solid, gas) : no data available Oxidizing properties : no data available Autoignition temperature : no data available pH : no data available Melting point/range / Freezing point : no data available Boiling point/boiling range : no data available Vapor pressure : no data available Density : ca.1.4 g/cm3 at 68 °F (20 °C) Water solubility : no data available Partition coefficient: n octanol/water : no data available Viscosity, dynamic : no data available Viscosity, kinematic : ca.> 20.5 mm2/s at 104 °F (40 °C) Relative vapor density : no data available Evaporation rate : no data available Burning rate : no data available Volatile organic compounds (VOC) content : 40 g/l

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

10. Stability and reactivity Reactivity

: No dangerous reaction known under conditions of normal use.

Chemical stability

: The product is chemically stable.

Possibility of hazardous reactions Conditions to avoid

: Stable under recommended storage conditions.

: no data available

Incompatible materials

: no data available

11. Toxicological information

Acute toxicity Product

Acute oral toxicity

: no data available

Acute inhalation toxicity

: no data available

Acute dermal toxicity

: no data available

Ingredients: aromatic polyisocyanate : Acute oral toxicity

: LD50 Oral rat: > 5,000 mg/kg

Carbon black : Acute oral toxicity

: LD50 Oral rat: > 8,000 mg/kg

4,4'-methylenediphenyl diisocyanate : Acute inhalation toxicity

: Acute toxicity estimate : 1.5 mg/l Test atmosphere: dust/mist Method: Expert judgment

Skin corrosion/irritation Product no data available

Serious eye damage/eye irritation Product no data available Respiratory or skin sensitization Product

May cause an allergic skin reaction.

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Safety Data Sheet Sikaflex®‐201 US 

Revision Date 07/29/2014

Print Date 08/07/2014

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

Germ cell mutagenicity Product Mutagenicity

: no data available

Carcinogenicity Product

Carcinogenicity

: May cause cancer.

IARC

Group 2B: Possibly carcinogenic to humans titanium dioxide 13463-67-7 ethylbenzene 100-41-4 Carbon black 1333-86-4 Group 1: Carcinogenic to humans Quartz (SiO2) 14808-60-7

NTP

Known to be human carcinogen Quartz (SiO2)

14808-60-7

Reproductive Toxicity/Fertility Product Reproductive toxicity

: no data available

Reproductive Toxicity/Development/Teratogenicity Product Teratogenicity : no data available

STOT-single exposure Product

Assessment: no data available

STOT-repeated exposure Reports have associated repeated and prolonged exposure to some of the chemicals in this product with permanent brain,liver, kidney and nervous system damage. Intentional misuse by deliberate concentration and inhalation of vapors may be harmful or fatal. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Product Assessment: no data available

Aspiration toxicity Product

no data available

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