Table6. Determinationof linearity–averageof duplicate resultson three separatedays (N=3).
Expectedvalues are the shaded rows:mg/L except for Cr,Mo, andSewhichareµg/L. The
lowest standards testedwere50%of theCal Std1 inTable5, in case someof these cells
appear truncated to fit in this table. ANi internal standardwas also tested.
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
Ni
Ge
0.25 0.25
0.5 0.5
0.75 0.75
1.25 1.25 1.5 1.5
5
5
10 10
15 15
30 30
23Na[2] Overall Recov. (%) 102.9 102.1 101.4 104.7 104.9 104.0 104.6 105.7 102.6 105.2 102.7 102.4 101.8 101.5 100.5 100.5 102.2 100.1
Overall RSD (%)
2.0
5.3
1.6 2.9
2.1 2.1
2.8 1.2
2.3 1.9
1.7 0.6
2.9 0.3
4.2 1.4
2.3 1.4
0.1
0.1
0.2 0.2
0.3 0.3
0.5 0.5
0.6 0.6
2
2
4
4
6
6
12 12
24Mg[2] Overall Recov. (%) 100.0 98.9
99.8 101.8 102.1 103.7 102.6 102.9 99.8 101.3 100.2 100.5 101.7 101.1 100.7 99.4 102.1 99.3
Overall RSD (%)
2.3
4.6
0.9 1.9
2.4 2.5
2.2 1.8
2.1 0.6
2.3 0.7
3.8 1.6
4.9 1.1
1.6 1.1
0.3
0.3
0.5 0.5
0.8 0.8
1.3 1.3
1.5 1.5
5.0 5.0
10.0 10.0 15.0 15.0 30.0 30.0
31P[2] Overall Recov. (%) 98.9 94.8
98.5 97.6
99.1 93.0
95.1 93.4 97.3 91.1 94.5 93.9 98.9 96.1 100.1 97.3 104.0 93.8
Overall RSD (%)
1.0
5.9
2.8 1.2
4.4 7.5
0.4 1.3
0.1 9.3
4.9 8.1
4.2 7.8
4.2 0.5
0.7 8.0
0.5
0.5
1.0 1.0
1.5 1.5
2.5 2.5
3.0 3.0 10.0 10.0 20.0 20.0 30.0 30.0 60.0 60.0
39K[2] Overall Recov. (%) 99.6 98.2
99.7 100.3 103.2 101.5 103.8 103.1 101.6 101.8 103.9 102.9 102.6 102.2 101.5 101.4 103.2 100.9
Overall RSD (%)
2.9
6.9
2.0 2.6
3.1 3.1
2.6 3.7
1.7 2.3
2.3 3.2
4.6 3.2
3.6 4.2
1.1 4.0
0.5
0.5
1.0 1.0
1.5 1.5
2.5 2.5
3.0 3.0 10.0 10.0 20.0 20.0 30.0 30.0 60.0 60.0
44Ca[2] Overall Recov. (%) 98.7 97.8
99.0 99.9 101.5 100.5 102.8 102.1 100.6 100.7 101.0 100.9 102.3 102.1 100.3 100.6 102.7 101.1
Overall RSD (%)
2.4
5.5
1.9 2.5
2.4 1.8
2.0 3.0
2.4 1.1
3.1 2.7
4.9 3.2
3.8 3.7
0.9 3.0
0.4
0.4
0.8 0.8
1.2 1.2
2.0 2.0
2.4 2.4
8.0 8.0
16.0 16.0 24.0 24.0 48.0 48.0
52Cr[2]] Overall Recov. (%) 100.2 100.2 98.0 100.1 100.6 102.0 100.8 101.5 101.0 103.0 100.5 101.8 101.4 101.5 100.0 100.9 100.4 98.9
Overall RSD (%)
0.4
7.2
4.1 5.4
1.3 0.5
0.7 1.6
0.4 1.8
0.3 1.0
1.2 0.6
2.1 1.2
2.7 2.7
0.0
0.0
0.0 0.0
0.0 0.0
0.0 0.0
0.0 0.0
0.1 0.1
0.1 0.1
0.2 0.2
0.3 0.3
55Mn[2] Overall Recov. (%) 99.3 99.9
99.8 101.1 102.0 101.7 102.4 102.3 101.8 101.9 101.9 101.9 102.0 102.4 100.9 101.4 101.4 99.6
Overall RSD (%)
2.4
5.8
2.4 3.1
1.3 1.2
1.3 1.2
1.2 0.8
1.1 1.5
3.3 1.6
0.7 1.2
1.0 1.2
0.0
0.0
0.1 0.1
0.1 0.1
0.1 0.1
0.2 0.2
0.5 0.5
1.0 1.0
1.5 1.5
3.0 3.0
56Fe[2] Overall Recov. (%) 103.9 105.0 103.5 106.1 103.0 106.7 105.1 106.5 104.8 106.6 105.3 105.5 101.6 104.7 99.2 99.4 101.5 98.3
Overall RSD (%)
0.7
8.9
6.8 7.1
2.0 4.1
1.9 2.9
1.9 3.3
5.0 4.3
1.3 5.0
2.9 1.7
1.1 1.4
0.0
0.0
0.0 0.0
0.0 0.0
0.0 0.0
0.0 0.0
0.1 0.1
0.1 0.1
0.2 0.2
0.3 0.3
63Cu[2] Overall Recov. (%) 102.6 101.6 99.1 101.9 100.6 101.1 101.5 102.9 100.5 101.9 99.4 101.6 100.3 100.4 99.8 99.3 98.2 96.3
Overall RSD (%)
1.8
6.8
4.0 6.1
1.3 3.2
1.0 2.8
0.5 2.8
0.4 1.9
0.3 1.8
2.7 3.0
0.7 3.1
0.0
0.0
0.0 0.0
0.0 0.0
0.1 0.1
0.1 0.1
0.2 0.2
0.4 0.4
0.6 0.6
1.2 1.2
66Zn[2] Overall Recov. (%) 100.0 98.6
98.4 100.6 98.3 99.5
100.4 101.1 98.6 100.6 98.1 99.7 100.9 101.2 101.5 100.0 103.0 98.1
Overall RSD (%)
1.2
7.6
4.9 6.6
2.7 1.9
1.5 2.1
1.3 2.9
0.7 2.0
0.9 1.5
3.9 2.0
1.5 2.0
0.4
0.4
0.8 0.8
1.2 1.2
2.0 2.0
2.4 2.4
8.0 8.0
16.0 16.0 24.0 24.0 48.0 48.0
95Mo[2] Overall Recov. (%) 97.9 97.7
97.4 101.2 97.7 103.7
97.6 98.3 99.4 100.7 99.5 100.7 100.3 100.6 98.2 99.7 100.1 98.8
Overall RSD (%)
2.1
7.5
0.0 2.9
4.3 4.0
2.6 3.5
2.6 0.8
1.9 1.3
0.7 1.2
2.0 2.2
0.7 2.2
Te
Te
Te
Te
Te
Te
Te
Te
Te
0.2
0.4
0.6
1.0
1.2
4.0
8.0
12.0
24.0
78Se[1] Overall Recov. (%)
100.0
97.3
98.2
96.6
99.4
100.0
99.0
99.4
99.9
Overall RSD (%)
3.4
2.8
2.0
3.3
1.4
1.2
0.5
2.2
1.2
[1] - Hydrogen gas mode
[2] - Helium gas mode
MTE-02
FORWORKINGGROUP/ERPUSEONLY
DONOTDISTRIBUTE
