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Ozone

Ozoneisaverystrongoxidizingagentthatdestroysorganiccompounds

that are especially difficult to oxidize. It allows the pool manager to very

efficiently remove combined chlorine without frequently refreshing

large amounts of pool water. By the time the water passes through

the filter units, ozone has already completed sanitizing, and it is not

effected by the pH level.

Mainly because of its strong oxidizing power, the return water may

contain trace concentrations of ozone. It imperative to know that

ozone is very unstable, so to ensure thorough sanitization of the

water, low-level chlorination remains necessary.

The Water Balance and Langelier Index

Pool water characteristics need to be maintained in a balanced state

to avoid numerous issues. Measuring certain variables is extremely

important to predict if the water is corrosive or will cause scaling.

A saturation index developed by Dr. Wilfred Langelier is widely used

to predict the balance of swimming pool waters. It represents the

estimation of a solutions ability to dissolve or precipitate calcium

carbonate deposits. A certain level of this precipitation (filming) is

desired to insulate pipes and boilers from contact with water. When no

protective filming is formed, water is considered to be corrosive. On the

other hand, too much filming can develop into scaling and incrustation

of the pipes.

In the treatment and monitoring of pool water, the pool manager

must ensure that related parameters such as alkalinity, hardness

and pH are carefully monitored in addition to sanitizing chemicals.

Calcium

The presence of calcium in the system is desired to ensure filming on

those places where the temperature is relatively high, like in boilers

and pipes transporting warm water. Scaling must be avoided because

it reduces heat transfer and pump capacity, and causes cloudiness in

the water.

It is recommended to maintain the calcium hardness value within the

range from 200 to 400 ppm as calcium carbonate (CaCO₃).

Alkalinity

Alkalinity is the measure of the total concentration of alkaline

substances, mostly bicarbonates, dissolved in the water. The higher

the alkalinity, themore resistant thewater is to pH change. At the same

time, high alkaline water is a major contributor to scaling problems like

incrustation in filtration equipment, pumps, and piping.

It is recommended to maintain the alkalinity value within the range

from 80 to 125 ppm as calcium carbonate (CaCO₃).

pH

The pH of the water is an important factor since at lower pH levels the

corrosion rate increases. If the alkalinity values are sufficiently high,

it will not be difficult to control the pH. Most pool managers prefer to

keep the pH between 7.2 and 7.4 to best maintain low corrosion rates

and a sufficient activity of chlorine.

10

Photometers

10.34

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