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FROZEN HEAT

68

How long a warming event takes to affect gas hydrate sta-

bility and whether methane released from gas hydrates is

transported to the atmosphere depend, to a large extent, on

where gas hydrates are located. Based on published distri-

bution estimates, Ruppel (2011) summarizes five general

categories or “zones” of gas hydrate occurrence and the

extent to which predicted climate change would result in

the transport of methane from gas hydrates to the atmos-

phere (Figure 3.10). Following the work of Ruppel (2011),

estimates of gas hydrate sensitivity to warming are given

as percentages of the global gas hydrate store, assuming

99 per cent of the world’s gas hydrates are located in deep-

water marine environments (zones 3-5 in Figure 3.10), and

1 per cent are associated with permafrost, either on land or

submerged in shallow Arctic shelf regions (zones 1 and 2 in

Figure 3.10) (McIver 1981). The percentages given by Rup-

pel (2011) depend on whether future studies uphold the as-

sumed balance between marine and permafrost-associated

gas hydrate volumes. For a sense of scale, even 1 per cent

of the estimated global supply of methane in gas hydrates

(5 000 GtC) is equivalent to 25 times the estimated global

consumption of methane in 2020 (2.15 GtC), based on con-

sumption estimates from the (U.S. Energy Information Ad-

ministration, 2010).

1: Terrestrial Arctic environments

Less than 1 per cent of the world’s gas hydrates are likely to

exist in this environment (Zone 1 in Fig. 3.10). Because the

presence of permafrost dramatically slows the transfer of

heat to the depths at which gas hydrates exist, time scales in

excess of 1 000 years are necessary for atmospheric warm-

ing to begin dissociating gas hydrates at the top of the gas

hydrate stability zone (Ruppel 2011). On an extremely local-

ized scale, thermokarst lakes may provide a conduit for more

rapid delivery of heat into the subsurface to dissociate gas

hydrates. Gas-venting pockmark features beneath delta lakes

and channels at the edge of the Mackenzie Delta have been

attributed to gas hydrate dissociation (Bowen

et al.

2008). As

noted in Ruppel (2011), however, methane seeps in terrestrial

Arctic environments may be carrying methane from deeper

hydrocarbon reservoirs, rather than from gas hydrates break-

ing down due to warming. Identifying the methane source in

this sector is an important research focus.

2: Flooded permafrost environments (<100

metres water depth)

Given the assumption that 1 per cent of the world’s gas hy-

drates exist in polar regions, and much of that 1 per cent

exists below terrestrial permafrost, Ruppel (2011) estimates

less than 0.25 per cent of the global gas hydrate volume is

found in flooded permafrost regions (Zone 2 in Fig. 3.10).

Gas hydrates in Zone 2 are also buried beneath about 200

metres of sediment, and it is not likely that human-activi-

ty-related warming trends are affecting them significantly.

However, this sector has experienced significant warming,

because coastal flooding that occurred about 13 500 years ago

generated up to 17 °C of warming (Shakhova

et al.

2010b) at

the sediment surface. This warming continues to thaw and

degrade both permafrost and underlying gas hydrates (Sem-

iletov

et al.

2004). In these shallow environments, methane

gas released from the sea floor can pass through the water

column and enter the atmosphere (McGinnis

et al.

2006).

This sector is a likely location for gas hydrates to impact the

atmospheric methane concentration over the next few hun-

dred years. However, identifying how much of the methane

release is caused by anthropogenic warming of gas hydrates

requires first distinguishing between methane produced by

gas hydrate dissociation and methane from other sources,

such as organic matter decay or migration from deeper

methane sources.

3.6

REVIEWOF SENSITIVITY OF

GLOBAL GAS HYDRATE INVENTORY

TO CLIMATE CHANGE