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19

LiD

FEB/MAR 2016

and – as an imperfect dark body emitter – radiates

energy across a continuous spectrum. Only a very

small part of that emission (about 2 to 3 per cent)

is as visible light. The rest we experience as heat.

And it is that lack of efficient visible light produc-

tion that makes incandescent lighting so wasteful

of electricity.

There are two low-energy alternatives, only

one of which you probably see in people's homes.

Fluorescent lighting is produced by a tube of

mercury-vapour which releases ultraviolet light in

response to an electrical current.That UV causes a

phosphor coating on the inside of the glass to glow.

They’re about 7 to 15 per cent efficient.

LEDs are a solid-state p-n junction diode which

emits light as a result of an electric field applied to

a semi-conductor.They’re about 5 to 20 per cent ef-

ficient and remain expensive.There’s still a great deal

of lost energy in each of these alternative solutions.

In the world of solar panels (really just the re-

verse of a light bulb – using broad-spectrum light

energy to create electricity), researchers have been

developing mechanisms to improve the range of en-

ergy wavelength that can be absorbed by solar cells.

Perovskite-structured materials increase energy

absorption by over 20 per cent.These aremethylam-

monium lead halides dissolved in a solvent and then

coated onto a substrate using vapour deposition.

Then there’s lanthanide doping to improve conver-

sion of infrared photons into higher energy photons.

Or light-absorbing dyes such as ruthenium.

Only one problem: all these specialist materials

start to fail after 1000 K. And our incandescent is

most productive much closer to 3000 K.

Professor Marin Solja

Č

i

Ć

and his team began

working on interference systems sandwiched

around the incandescent emitter (for want of bet-

ter terms, they refer to these as the cold and hot

sides respectively).

‘In general,’ they declare, ‘the emissivity of a

high-temperature emitter depends on temperature

and wavelength.’ By surrounding the emitter with

an interference structure designed to transmit vis-

ible light and recycle infrared light across a wide

range of emission angles they hoped to improve

the efficiency of the system.

Simply put, all that radiated non-visible energy

can be transformed into visible light if we can only

absorb it in some way and recycle it back into the

emitter to reduce the initial energy required to heat

the light source. As a very bad analogy, consider how

much less energy it takes to heat water in a thermos

versus when the water is flowing past in a pipe.

‘An ideal lighting source would then be a hypo-

thetical high-temperature black body that emits only

visible wavelengths. Such an emitter would have

a luminous efficiency of approximately 40-45%,’

says Solja

Č

i

Ć

.

The problem, as mentioned earlier, is that exist-

ing incandescents are not ideal black body emitters

and the current approaches to absorption fail at

high temperatures.

What Solja

Č

i

Ć

and his teamwere looking for was

an interference stack, like a thin film, that could ab-

sorb a wide range of wavelengths and angles (since

incandescent light is not particularly linear), that is

able to efficiently reabsorb non-visible energy radia-

tion while being subjected to resistive heating, and

still be compatible with thermal emitters.

They selected four materials: SiO

2

, Al

2

O

3

, Ta

2

O

5

and TiO

2

.

The next step was to create a film that would

act appropriately.They chose what is called a rugate

filter, which is based on a dielectric coating where

the refractive index varies continuously as part of

its structure. Dielectric coatings themselves are

thin-film or interference coatings composed of

sub-micron layers of transparent dielectric materi-

als. These can be placed by vapour deposition on

a substrate (like glass).

They are used to modify the reflective proper-

ties of a surface by exploiting the interference of

reflections from an optical source. At its simplest,

rugate filters have a sinusoidal oscillation of the re-

fractive index.This creates a notch filter (or multiple

notches), blocking a limited wavelength range and

reflecting it back onto the emitter.

There is a great deal of mathematics in the

Solja

Č

i

Ć

paper since, as you can imagine, fine-tuning

the properties of the materials and the rugate filter

(and its numerous notches) is supremely complex.

Solja

Č

i

Ć

and co then went ahead and built a

proof-of-concept. It’s actually quite pretty.

The rugate filter consists of ninety layers of

SiO

2

andTa

2

O

5

and the usual tungsten filament was

made to maximise reabsorption (making it into a

highly-polished and flattened radiator-like structure).

They then measured the luminous efficiency as

being 6.6 per cent, already significantly better than

existing incandescents and reaching the levels of

low-end LEDs.

Theoretically, they could achieve 40 per cent.

The more efficient the reflection of non-visible light

back to the tungsten filament, themore heat ismain-

tained in the system so the more energy-efficient it

becomes at converting heat into visible light.