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492

M

ASTOVSKA

ET AL

.

J

OURNAL OF

AOAC I

NTERNATIONAL

V

OL

. 98, N

O

. 2, 2015

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conditions.

(

c

)

Injection sequence.

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H. Calculations

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RI DQDO\WH VLJQDOV

S

PAH

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)

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see

Table

2014.08I

) plotted versus analyte concentrations.

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are not well resolved, such as in the case of anthracene and

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(

c

PAH

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c

PAH

>

S

PAH

S

& 3$+

±

b

@

a

where

a

is the slope of the calibration curve and

b

is the

y

LQWHUFHSW

The concentration of PAHs in the sample (

C

—J NJ LV WKHQ

FDOFXODWHG

C

= (

c

PAH

c

& 3$+

î

X

& 3$+

m

)

where

c

& 3$+

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& 3$+ LQ WKH FDOLEUDWLRQ VWDQGDUG VROXWLRQV LQ —J /

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on the method procedure and preparation of the calibration

standard solutions,

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& 3$+

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LV QJ DQG

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a

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DQG

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2

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concentration levels, a limited calibration curve (without

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Results and Discussion

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physicochemical properties and occurrence in the environment

and various materials that can lead to contamination issues.

PAH properties, such as their volatility, polarity, and structure,

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technique, equipment, or conditions. For this reason, they

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the silica deactivation), and evaporation conditions (to avoid

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very important consideration for the future implementation of

the method in other laboratories.

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contamination. The concentrations of all analytes in the

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calibration level standard. For naphthalene, levels below the

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naphthalene in the sample) were still acceptable if the source of

contamination could not be eliminated, such as by selection of

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Table 2014.08I. PAH analytes and corresponding

13

C

-PAHs used for PAH signal normalization

Analyte

13

C

3$+ XVHG IRU VLJQDO QRUPDOL]DWLRQ

Anthracene

$QWKUDFHQH

13

C

6

Benz[

a

]anthracene

Benz[

a

@DQWKUDFHQH

13

C

6

Benzo[

a

]pyrene

Benzo[

a

@S\UHQH

13

C

4

Benzo[

b

@ÀXRUDQWKHQH

Benzo[

b

@ÀXRUDQWKHQH

13

C

6

Benzo[

g,h,i

]perylene

Benzo[

g,h,i

@SHU\OHQH

13

C

12

Benzo[

k

@ÀXRUDQWKHQH

Benzo[

k

@ÀXRUDQWKHQH

13

C

6

Chrysene

&KU\VHQH

13

C

6

Dibenz[

a,h

]anthracene

Dibenz[

a,h

@DQWKUDFHQH

13

C

6

)OXRUDQWKHQH

)OXRUDQWKHQH

13

C

6

)OXRUHQH

)OXRUHQH

13

C

6

Indeno[1,2,3-

cd

]pyrene

Indeno[1,2,3-

cd

@S\UHQH

13

C

6

Naphthalene

1DSKWKDOHQH

13

C

6

Phenanthrene

3KHQDQWKUHQH

13

C

6

Pyrene

3\UHQH

13

C

6

1-Methylnaphthalene

1DSKWKDOHQH

13

C

6

2,6-Dimethylnaphthalene

3KHQDQWKUHQH

13

C

6

1-Methylphenanthrene

3KHQDQWKUHQH

13

C

6

1,7-Dimethylphenanthrene

3KHQDQWKUHQH

13

C

6

3-Methylchrysene

&KU\VHQH

13

C

6