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13

Chemical Technology • September 2015

Determining the effect of augmented winery wastewater

on the chemical properties of four different soils in a pot trial

also formed part of the project and results are discussed in

the final report.

Soil chemical status

Field trial

Soil samples were collected in the work rows of selected

treatments after the application of wastewater irrigations

in May, and again from all treatments at bud break, ie, fol-

lowing winter.

Although there were no clear trends in soil pH, EC or acid-

ity, ECwas substantially higher after the seasonal wastewater

irrigations compared to bud break. This was probably due to

the higher salt content in the augmented wastewaters.

There was a close correlation between P applied via the

irrigation water and the P levels in the 0 to 30 cm soil layer in

the work row. Under the prevailing conditions, soil K increased

with a decrease in the dilution of the wastewater during all

four seasons.

After four years, only the lowest level of augmentation, ie,

3 000 mg/ℓ COD, maintained baseline K levels. Soil Ca and

Mg did not show any consistent responses to the different

levels of wastewater augmentation because there were no

substantial different to amounts of these particular elements

applied via the irrigation water.

Generally, soil Na increased with a decrease in the dilution

of the wastewater. There were substantial differences in the

amount of Na applied via the irrigation water. Although irriga-

tionwithwinery wastewater had almost no other effects under

the prevailing conditions, element accumulation, particularly

with respect to K and Na, might bemore prominent in heavier

soils or in regions with low winter rainfall.

Element uptake and removal

Cover crops, ie, oats and pearl millet were established in

the work rows during winter and summer, respectively. The

dry matter production (DMP) and element content of the

above-ground growth of these crops was determined over

a period of four and three years, respectively.

Oats tended to produce more dry matter when irrigated

with augmented winery wastewater compared to raw wa-

ter irrigation, if not preceded by pearl millet as a summer

interception crop. Oats continuously produced acceptable

amounts of fibre.

The levels of Ca, Mg and K in the above-ground growth

did not differ between treatments. Although differences oc-

curred, no trends with respect to level of augmentation were

WATER TREATMENT