450-451 / 620
Table 2
Nominal
T
stat
p
-value
80.4
0.8
81.8
-0.6
81.2
0.0
80.5
0.7
81.8
-0.6
82.2
-1.0
82.3
-1.1
81.9
-0.7
83.0
-1.8
Mean
81.7
-0.5
SD
0.8
0.8
T
stat
=
where: = mean of the differences between measured results and reference value
sd = standard deviation of the differences between results and reference value
n
= number of replicate analyses of SRM
H
0
: = 0, The null hypothesis is that there is no difference between the measured results and the certified value:
p
-value: is the probability (at the 95% levels of confidence) of obtaining the test statistic assuming that the null hypothesis is true.
p
-value < 0.05 indicate a difference of statistical signifance between measured results and SRM.
95% confidence interval: The true population of the measured value expected to fall within the confidence interval estimate 95% of the time.
lower limit = mean -
upper limit = mean +
where: = critical values of the t-distribution
sd = standard deviation of the differences between results an reference value
n
= number of replicate analyses of SRM
81.0 - 82.3
Bias
Confidence interval
0.5
1.693
0.129
SRM 1849a
Se (µg/100g)
81.2
2.9
78.3 - 84.1
Accuracy - Analytical bias compared to reference material
Certified Reference Material
Measured Results
CRM product
Analyte
Certified value Uncertainty Certified range Concentration
Difference from
certified value
n
/
sd
d
d
d
n
t
crit
sd
n
t
crit
sd
crit
t
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