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19

March 2017

AFRICAN FUSION

Steel

Welding 5% Ni steel

Welding 9% Ni steel

DIN EN ISO

15609-1

AWS- Norm

Product (and current)

AWS-Standard

Product (and current)

SMAW

process 111

E316L-15 (Mod)

Thermanit 19/15

E NiCrMo-6

UTP Soudonel D (AC/DC+)

E NiCrMo-6

UTP Soudonel D (AC/DC)

E NiCrMo-3

UTP 6222 Mo (DC+)

E NiCrMo-6

UTP 7013 Mo (AC/DC)

E NiCrMo-6

UTP 7013 Mo (AC/DC+)

SAW

process 12

Wire/flux

n.a.

Thermanit 17/15 TT + Marathon 104

Thermanit 19/15 + Marathon 104

ER NiCrMo-3

UTP UP 6222 Mo +

UTP UP Flux 6222 Mo (AC/DC+)

Thermanit 625 +

Marathon 104 (AC/DC+)

ER NiCrMo-4 Thermanit Nimo C276 +Marathon 104

(AC/DC 1,6 mm and AC 2,4 mm)

ER NiCrMo-4 Thermanit Nimo C276 +Marathon 104

(AC/DC+ 1,6 mm and AC 2,4 mm)

GMAW

process 135

n.a.

Thermanit 17/15 TT (DC+)

ER NiCrMo-3

UTP A 6222 Mo (DC)

Thermanit 625 (DC+)

FCAW

process 136

ENiCrMo-3 T1-4

UTP AF 6222 Mo PW (DC/AC)

ENiCrMo-3 T1-4

UTP AF 6222 Mo PW (DC+/AC)

Consumables for welding 5% and 9% Ni tanks.

describing low temperature toughness

behaviour of a metal.

Simply explained, lateral expansion

is a measure of the plastic deformation

of a material during impact testing. The

most common requirement for lateral

expansion is a minimum of 0.38 mm.

There is in general a linear correlation

between impact toughness and lateral

expansion. The higher the impact tough-

ness (joules, J), the higher the value of

lateral expansion. This correlation is also

influenced by the welding process and

slag-systems.

Welding of 9% Ni Steel

The 9% nickel steels used in LNG stor-

age tanks are quenched and tempered

or so-called double nor-

malised and tempered. The

latter involves heat treat-

ment in which the steel is

heated to the two-phase

region several times and

thus undergoes partial aus-

tenitising. During this heat

treatment, the small aus-

tenite areas absorb, through

diffusion, large amounts of

the available carbon and

nitrogen. Consequently,

carbon and nitrogen con-

tents in the martensite/

ferrite are reduced and both

hardness andbrittleness are

decreased. The high carbon

and nitrogen contents also

contribute to the austenite

areas remaining stable at

lower temperatures. This

gives the steel its excel-

lent toughness at cryogenic

temperatures. Martensite

that is not converted into austenite is,

of course, also tempered during heat

treatment, thereby also contributing to

the increased toughness of this phase of

the structure’s material.

When it comes towelding 9%nickel,

the options are matching and non-

matching filler metals. For nearly all

actual fabrication, non-matching fillers

are chosen. This is due to the need to

match the thermal expansion of the par-

ent material, while optimising the weld

metal strength. Nickel alloys match this

requirement closer than stainless steels.

Welding must be done with the par-

ent plates fully restrained to prevent

weld strength being lost after distortion.

9% Ni steel can be prepared for

welding by flame cutting and grinding.

Weld joints need to be slightly wider

than for conventional steels to ensure

good root access and to accommodate

the sluggish behaviour of the nickel-

based welding consumable. The most

commonly applied welding methods

are SMAW, SAW and FCAW and depend-

ing on the region, GTAW. The strong

magnetic nature of 9% Ni can pose arc

blowproblems, which can be controlled

by applying alternatingwelding current

(ac) and by demagnetising on site. Pre-

heating of the weld zone is not neces-

sary although the maximum inter-pass

temperature should be limited to a

maximum of 150 °C.

In tank construction, stick elec-

trodes and flux-coredwire are predomi-

nantly used for vertical (PF, 3G) welds

and submerged-arc welding for hori-

zontal (PA, 1G) and horizontal-vertical

(PC, 2G) welds.

Because the 9%nickel steels contain

a certain amount of austenite, there is

little risk of hydrogen cracking. Filler

metals that give an austenitic or nickel-

based weld metal absorb hydrogen

easily. Nonetheless, to minimise the

width of the heat-affected zone (HAZ),

the heat input during welding is usu-

ally restricted to 2.0 kJ/mm. The HAZ is

kept as narrow as possible because the

favourable structure of the parentmetal

would typically be destroyed here.

Anotherwelding recommendation is

applying multi-pass welding to achieve

‘weld normalisation’ of the HAZ. For the

weldmetal to acquire the desired tough-

ness at low temperatures, nickel-based

filler metal must be used. For welding

of 5% and 9% Ni steel, the most com-

monly used consumables are covered