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© 2015 AOAC INTERNATIONAL

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Analyte

13

C

-PAH used for signal normalization

Anthracene

Anthracene (

13

C

6

)

Benz[

a

]anthracene

Benz[

a

]anthracene (

13

C

6

)

Benzo[

a

]pyrene

Benzo[

a

]pyrene (

13

C

4

)

Benzo[

b

@ÀXRUDQWKHQH

Benzo[

b

@ÀXRUDQWKHQH

13

C

6

)

Benzo[

g,h,i

]perylene

Benzo[

g,h,i

]perylene (

13

C

12

)

Benzo[

k

@ÀXRUDQWKHQH

Benzo[

k

@ÀXRUDQWKHQH

13

C

6

)

Chrysene

Chrysene (

13

C

6

)

Dibenz[

a,h

]anthracene

Dibenz[

a,h

]anthracene (

13

C

6

)

Fluoranthene

Fluoranthene (

13

C

6

)

Fluorene

Fluorene (

13

C

6

)

Indeno[1,2,3-

cd

]pyrene

Indeno[1,2,3-

cd

]pyrene (

13

C

6

)

Naphthalene

Naphthalene (

13

C

6

)

Phenanthrene

Phenanthrene (

13

C

6

)

Pyrene

Pyrene (

13

C

6

)

1-Methylnaphthalene

Naphthalene (

13

C

6

)

2,6-Dimethylnaphthalene

Phenanthrene (

13

C

6

)

1-Methylphenanthrene

Phenanthrene (

13

C

6

)

1,7-Dimethylphenanthrene

Phenanthrene (

13

C

6

)

3-Methylchrysene

Chrysene (

13

C

6

)

where

c

13C-PAH

is the concentration of the corresponding

13

C-PAH in

WKH FDOLEUDWLRQ VWDQGDUG VROXWLRQV LQ —J /

X

13C-PAH

is the amount

of the corresponding

13

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m

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preparation of the calibration standard solutions,

c

13C-PAH

LV —J /

X

13C-PAH

LV QJ DQG

m

IRU WKH WHVW VDPSOHV LV J

In the collaborative study, eight concentration levels were used

IRU WKH FDOLEUDWLRQ FRUUHVSRQGLQJ WR

DQG

—J / IRU EHQ]R>

a

]pyrene and other lower-level PAHs, to

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DQG —J / &RHI¿FLHQWV RI GHWHUPLQDWLRQ U

2

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WKH FDOLEUDWLRQ VWDQGDUGV VKRXOG QRW H[FHHG “ RI WKHRUHWLFDO )RU

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If a well-characterized quadratic relationship occurs, then a best-

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WKH EDFN FDOFXODWHG FRQFHQWUDWLRQV H[FHHG “ RI WKHRUHWLFDO

normalized signals of the nearest two calibration standards that

enclose the analyte signal in the sample can be used to interpolate

WKH DQDO\WH FRQFHQWUDWLRQ LQ WKH ¿QDO H[WUDFW

5HIHUHQFHV

.DODFKRYD . 3XONUDERYD - 'UDERYD /

&DMND 7 .RFRXUHN 9 +DMVORYD -

Anal. Chim. Acta

707

± KWWS G[ GRL

RUJ

M DFD

J. AOAC Int

.

98

'2,

MDRDFLQW

Posted: April 30, 2015