August 2016
AFRICAN FUSION
19
Figure 10: Complex structure of graphite inclusion, visible on
an over-etched surface (high resolution SEM image, original
magnification 26 790×).
coupon failed through the graphitised HAZ.
• Prolonged heat treatment at 635°C, at times for up to 1 200
hours, resulted in spheroidisation, but not in noticeable
graphitisation.
• Repair welding on graphitised material can be performed
successfully.
References
[1] Foulds JR and Viswanathan R: “Graphitization of steels
in elevated-temperature service”; Journal of Materials
Engineering and Performance, vol. 10, pp. 483-492,
Aug. 2000.
[2] Meier A, Hammerschmidt DandSkibbe E: “Graphitization
effects on high temperature ductwork”; Energytech, p.5,
2014.
[3] Samuals LE: “Light Microscopy”; pp. 165-183, 1999.
[4] Okada M: “Graphitization of weld heat-affected zone in
carbon steel”; Transaction of the Japan Institute of Met-
als, pp. 353-359, 1982.
[5] Dennis, W: “Heterogeneous Nucleation of Graphite in
Hypo-EutectoidSteel”; Iron andSteel Institute, pp. 59-64,
1952.
[6] Harry E: “Subcritical decomposition of carbide phase in
some low-carbon silicon steels”; The Journal of the Iron
and Steel Institute, pp. 109- 112, 1954.
[7] Brown F: “Nucleation of Graphite in Steel”; Welding
Journal, pp. 257-261, 1954.
[8] He K: “An electron microscopic study of spheroidal
graphite nodules formed in a medium-carbon steel by
annealing”; Acta Materialia, pp. 2919-2927, 2007.
[9] Foulds JRandShingledecker JP: “Anupdatedassessment
of graphitization of steels in elevated temperature ser-
vice”; Journal of Materials Engineering andPerformance,
vol. 24 no. 2, pp. 586-597, Dec. 2014.
[10] Moss C: “Graphitization in type A201 carbon steel in
petro- chemical plate after long term service”; Aus-
tralian Nuclear Science and Technology Organisation,
pp. 351‑359, 1994.
[11] ASME Boiler and Pressure Vessel Code: vol. IX, Welding,
Brazing and Fusing Qualifications, 2013.
[12] Toft L and Marsden R: “The Structure and Properties
of 1%Cr- 0.5%Mo Steel”; The Iron and Steel Institute,
276‑294, 1963.




