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COMMITTEE DRAFT

ISO/CD 15151 | IDF 229

12

© ISO 2010

All rights reserved

Table B.1 — Selected emission wavelengths and second check wavelengths and interferences

for determination by ICP-AES.

Element

Wavelength of

emission

(nm)

Sort of

“line”

Interfer

ence

Ca

210.324

211.276

317.933

422.673

Ion

Ion

Ion

Atom

Y

Cu

324.754

327.395

Atom

Atom

Ti, Fe

Fe

238.204

259.940

239.563

Ion

Ion

Ion

K

766.491

769.897

Atom

Atom

Mg

279.800

285.213

Ion

Atom

Fe

Mn

257.610

293.306

259.372

Ion

Ion

Ion

Fe, Mo,

Cr,

Al, Fe

Na

588.995

589.592

Atom

Atom

Ar

P

213.618

214.914

Atom

Atom

Cu, Fe,

Mo, Zn

Cu, Al,

Mg

Zn

202.548

213.857

Ion

Atom

P

Y

(internal

standard)

360.074

410.237

Ion

Atom

*Other lines of appropriate sensitivity, free of interferences or corrected for interferences in specific matrixes may be as just as

acceptable.

B.3

Quantification

B.3.1 General

As spectroscopic techniques are not able to measure concentrations directly, but by means of a

conversion of the emission signal into concentration, calibration is inevitable. Calibration can be

performed by means of a calibration curve.

B.3.2 Calibration curve

A calibration curve is constructed by adding increasing amounts of the substance to be studied to a

solution of a supporting matrix. The most difficult condition to meet is making the solutions used for

MTE-03 Addendum

FOR ERP USE ONLY

DO NOT DISTRIBUTE