9.7.2014 SPSFAM Meeting Book - page 58

What is speciation?
The sorting of an element into the chemical groups 
that are present in a sample.
Arsenic can be sorted into two main categories and 
then further examined by 
Inorganic arsenic
Arsenite → As 
3+ 
in AsO
3
3‐
A t → A
5+
i A O
3
rsena e 
n s
4
Organic arsenic (monomethylarsonic acid ‐ MMAA,
dimethylarsenic acid ‐ DMAA, arsenobetaine, 
dimethylarsinoylribosides, etc.)
Toxicity and Speciation
Variations in toxicity for mercury and arsenic species 
are well known.  Many other elements have similar 
variations in toxicity that arise from particular species.
1...,48,49,50,51,52,53,54,55,56,57 59,60,62-63,64,65,66,67,68,69,70,...89
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